Coach Japheth Munala's charges battled hard, but the Europeans proved to be too much for the 10-time African champions. They lost 3-0 (24-14,25-13,25-12) to Brazil in their opening match on Wednesday.
Kenya will battle Japan in their final preliminary match on Saturday at 10pm.
National women's volleyball team, Malkia Strikers, lost their second Pool B match of the Paris Olympics after going down 3-0 (25-14,25-17,25-15) to Poland at the South Paris Arena on Wednesday.
Edith Wisa and Pamella Owino strikes gave Malkia Strikes a 3-1 lead against the 1964 and 1968 Olympic Games bronze medallist, but poor reception saw the Kenyan at the back foot 4-3.